Large-scale micron-order 3D surface correlative chemical imaging of ancient Roman concrete.

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  • Author(s): Maragh JM;Maragh JM; Weaver JC; Weaver JC; Masic A; Masic A
  • Source:
    PloS one [PLoS One] 2019 Feb 06; Vol. 14 (2), pp. e0210710. Date of Electronic Publication: 2019 Feb 06 (Print Publication: 2019).
  • Publication Type:
    Historical Article; Journal Article
  • Language:
    English
  • Additional Information
    • Source:
      Publisher: Public Library of Science Country of Publication: United States NLM ID: 101285081 Publication Model: eCollection Cited Medium: Internet ISSN: 1932-6203 (Electronic) Linking ISSN: 19326203 NLM ISO Abbreviation: PLoS One Subsets: MEDLINE
    • Publication Information:
      Original Publication: San Francisco, CA : Public Library of Science
    • Subject Terms:
    • Abstract:
      There has been significant progress in recent years aimed at the development of new analytical techniques for investigating structure-function relationships in hierarchically ordered materials. Inspired by these technological advances and the potential for applying these approaches to the study of construction materials from antiquity, we present a new set of high throughput characterization tools for investigating ancient Roman concrete, which like many ancient construction materials, exhibits compositional heterogeneity and structural complexity across multiple length scales. The detailed characterization of ancient Roman concrete at each of these scales is important for understanding its mechanics, resilience, degradation pathways, and for making informed decisions regarding its preservation. In this multi-scale characterization investigation of ancient Roman concrete samples collected from the ancient city of Privernum (Priverno, Italy), cm-scale maps with micron-scale features were collected using multi-detector energy dispersive spectroscopy (EDS) and confocal Raman microscopy on both polished cross-sections and topographically complex fracture surfaces to extract both bulk and surface information. Raman spectroscopy was used for chemical profiling and phase characterization, and data collected using EDS was used to construct ternary diagrams to supplement our understanding of the different phases. We also present a methodology for correlating data collected using different techniques on the same sample at different orientations, which shows remarkable potential in using complementary characterization approaches in the study of heterogeneous materials with complex surface topographies.
      Competing Interests: The authors have declared that no competing interests exist.
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    • Publication Date:
      Date Created: 20190207 Date Completed: 20191113 Latest Revision: 20200309
    • Publication Date:
      20220902
    • Accession Number:
      PMC6364879
    • Accession Number:
      10.1371/journal.pone.0210710
    • Accession Number:
      30726243